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With the emergence of long life synthetic lubricants,
oil analysis is becoming an increasingly popular tool for monitoring the
serviceability of the lubricant as well as foreshadowing developing
problems. As synthetic lubricants are recommended for eight to ten times
the life of petroleum lubricants, a good oil analysis program is a must
for assuring that there is no contamination or degradation of the
lubricant and that it can continue to function for the extended drain
interval.
The Summit Industrial
Products Analysis Program is designed to give a complete overall view of
the physical and chemical characteristics of the lubricant to determine
any significant lubricant deterioration as well as detect any machinery
problems before they become serious and expensive to repair.
These benefits can only be realized through proper evaluation and
interpretation of analysis results.
All the test results must be considered, along with the user's
knowledge of his compressor's performance history, to correctly diagnose
the condition of a given oil sample.
Although there are given interpretations and recommendations on
each lab report returned, it is very helpful for the end user to have a
working knowledge of the tests involved and their significance.
VISCOSITY:
The viscosity of a lubricant is monitored for significant
increases or decreases from the original specification.
A substantial decrease in viscosity could indicate a
contamination of the lubricant causing a diluting effect. An increase in
viscosity could also indicate a contamination or a degradation of the
oil due to oxidation.
A change of viscosity of more than 10% from the original
specification usually indicates that the oil should be replaced.
TAN
(TOTAL ACID NUMBER):
The TAN of a lubricant measures the amount of acid and
acid-acting constituents in the lubricant.
This does not necessarily denote metal corroding materials as
many chemicals and additives used in lubricants have an acid number.
Increases
in TAN from the original specification usually indicates oil oxidation
or corrosive acid contamination.
A sudden increase in TAN can also indicate mechanical problems.
An increase in TAN to greater than two (2) is significant in a
compressor lubricant and would require the lubricant be changed.
WEAR
METALS:
In monitoring wear metals, it should be observed that the
significant factor is not so much the amount of metals present as the
rate of wear with respect to time.
A sudden increase in wear metals usually indicates an incipient
wear problem and machine inspection is highly recommended.
A slow, constant increase in wear metals, however, can be
considered normal for most equipment and no cause for alarm or required
action.
These metals will usually show in the form of iron, lead, copper,
chromium, aluminum, nickel, silver or tin.
ADDITIVE
METALS:
Additive metals tend to remain fairly stable over the life of the
lubricant but can fluctuate by 20 percent under normal circumstances.
The emergence of an element which was not present in the original
sample could indicate the addition of make-up oil whose additives differ
from the original product.
These metals are usually phosphorous, zinc, calcium, barium,
molybdenum or antimony. Silicon
is also used as an oil additive but can indicate the presence of dirt as
well.
WATER
CONTENT:
The presence of water in a lubricant can decrease its lubricating
effectiveness significantly; therefore, a lubricant should be monitored
for percent water volume.
The limit for water is virtually none and is typically measured
down to 0.10.
Possible Sources of Elements in Oil
-
Aluminum (Al) -
Pistons, bearings, bushings, pump vanes, blower/turbos, washers,
dirt, shims
-
Antimony (Sb) - Babbitt bearings, greases
-
Barium (Ba) - New oils(dispersant/detergent), grease,
water
-
Boron (B) - New oils,coolant, seals, dust, fuel dilution
-
Cadmium (Cd) - Bearings,platings
-
Calcium (Ca) - New oils(dispersant/detergent), water,
grease
-
Chromium (Cr) - Plated parts (primarily piston rings),
coolant, anti-friction bearings, shafts, gears, seals, bearing
cages, fuel leaks gas turbines
-
Cobalt (Co) - Bearings, turbine components
-
Copper (Cu) - Bearings,bearing cushions, bushings,
thrust washers, valves, guides, injector shields, oil cooler
tubes, wet clutches, coolant (copper radiator), gears
-
Iron (Fe) - Rings, crankshaft, cylinder walls, valve
train, pistons, anti-friction bearings, gear train, shafts, clutch
plates, washers, rust, water
-
Lead (Pb) - Babbitt or copper-lead bearings, platings,
leaded gear lubes, leaded gasoline, grease, paint, seals, solder
-
Magnesium (Mg) - New oils (dispersant/detergent),
bearings, superchargers, water
-
Manganese (Mn) - Steels, shafts, valves, corrosion,
blowers (exhaust & intake systems)
-
Molybdenum (Mo) - Additives, piston rings, electric
motors
-
Nickel (Ni) - Shafts, valves, anti-friction bearings,
gears, rings, turbine components
-
Phosphorous(P) - New oils, (anti-wear additives), gears,
coolant leaks.
-
Silicon (Si) - Sand, dirt, dust, anti-foam, anti-freeze,
gasket sealing compounds
-
Silver (Ag) - Anti-friction bearings, silver solder,
wrist pin bushings, gear teeth, shafts
-
Sodium (Na) - Some new oils, coolant, salt water, grease
-
Tin (Sn) - Babbitt bearings, platings, solder, coolers,
wrist pins, pistons, rings
-
Titanium (Ti) - Wear turbine engines, springs, valves,
bearing hub, compressor discs, turbine blades
-
Vanadium (V) - By product heavy fuel oil, occasionally
wear metal, turbine blades, valves
-
Zinc (Zn) - Anti-oxidant, anti-corrosive, anti-wear
agent, bearings, platings, gears, seals, coolant leaks, grease.
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